作者投稿
专家审稿
编辑办公
Research Progress on Cosmetic Matrix Reference Materials
-
摘要: 近10年来，化妆品质量安全问题日益成为广大消费者关注的焦点，许多知名品牌化妆品被报道检出含有禁限用物质，不仅损害了消费者权益，给化妆品企业带来了经济损失，也对化妆品监管机构和化妆品质量安全检验检测机构提出了挑战。化妆品基体标准物质由于具有真实样品的特性，普遍用于与其有相同或相似基体的化妆品分析方法开发和评价、实验室能力验证以及定性定量分析过程的质量控制，对于保证检测结果的准确性、可靠性和溯源性具有不可替代的作用，是分析领域重要的“计量器具”。对1993年至今我国化妆品基体标准物质的发展状况进行了综述，从化妆品定义及分类入手，对化妆品基体标准物质的添加目标物种类、基质类型、标准物质定级等方面进行了分析，并在提出该领域研究面临的主要问题的基础上，对化妆品基体标准物质的需求与趋势进行了展望，提出解决制约化妆品基体标准物质发展的方法，旨在为后续化妆品基体标准物质研究提供一定的参考与借鉴。Abstract: Over the past decade, cosmetic quality and safety issues have increasingly become a focus of consumer concern. Many well-known cosmetic brands have been reported to contain prohibited or restricted substances, not only harming consumer interests and causing economic losses to cosmetic companies but also challenging regulatory agencies and quality inspection institutions. Cosmetic matrix reference materials, due to their similarity to real samples, are widely used in developing and evaluating analytical methods for cosmetics with similar matrices, laboratory proficiency testing, and quality control of qualitative and quantitative analyses. They play an irreplaceable role in ensuring the accuracy, reliability, and traceability of test results, serving as important "measurement instruments" in the analytical field. This article reviews the development of cosmetic matrix reference materials in China from 1993 to the present. Starting from the definition and classification of cosmetics, it analyzes aspects such as the types of target additives, matrix types, and grading of reference materials. Based on the main challenges faced in this field, it anticipates the demand and trends for cosmetic matrix reference materials and proposes solutions to constraints on their development, aiming to provide references for future research on cosmetic matrix reference materials.
-
Key words:
- matrix reference material /
- certified reference material /
- cosmetics /
- metrology
-
图 1 化妆品基体有证标准物质研制情况
Figure 1. Characteristics of certified reference materials for cosmetic matrices
图 2 化妆品基体有证标准物质供给情况
Figure 2. Supply of certified reference materials for cosmetic matrices
-
[1] 孟丽萱, 张伟, 鄢园姣, 等. 化妆品植物原料安全性研究进展[J]. 中国化妆品, 2024(2): 80-83. [2] 王亚峰, 郭沈涛, 邓淑鸿, 等. 化妆品原料光甘草定的安全性评估[J]. 香料香精化妆品, 2023(6): 96-101. [3] 刘敏, 黄湘鹭, 邢书霞. 化妆品中曲酸的安全性评价进展[J]. 香料香精化妆品, 2023(3): 7-9,35. [4] 赵倩茹, 刘骅, 孟雅萍, 等. 超高效液相色谱-串联质谱法同时测定化妆品中83种糖皮质激素[J]. 色谱, 2023, 41(12): 1084-1094. [5] 芦丽, 方方, 冯有龙, 等. 前体离子扫描超高效液相色谱-三重四级杆串联质谱法快速筛查化妆品中非法添加的磺胺类药物[J]. 日用化学工业(中文), 2024, 54(2): 216-223. [6] 殷帅, 尹伟成, 张伟清, 等. 化妆品中52种禁用抗组胺类药物高分辨质谱数据库建立与应用[J]. 香料香精化妆品, 2023(4): 116-120. [7] 牛水蛟, 于海英, 董亚蕾, 等. HPLC-MS/MS法测定化妆品中非法添加的他克莫司和吡美莫司[J]. 药物分析杂志, 2023, 43(10): 1759-1765. [8] 贺丽英. 固相萃取-超高效液相色谱-串联质谱法同时测定化妆品中24种抗真菌组分[J]. 香料香精化妆品, 2023(5): 158-165. [9] 薛晶, 杨青云, 黄宝斌. 浅析《化妆品补充检验方法研究起草技术指南》[J]. 日用化学工业(中英文), 2023, 53(2): 187-192. [10] 刘丽, 王常禹, 姜连阁, 等. 牙膏及化妆品检验中标准物质及其储备液的管理[J]. 口腔护理用品工业, 2022, 32(5): 12-17. doi: 10.3969/j.issn.2095-3607.2022.05.003 [11] 卢晓华, 薄梦, 吴雪, 等. 标准物质领域发展现状及趋势[J]. 化学试剂, 2022, 44(10): 1403-1410. [12] 吴利君, 尹营, 戴丽雪, 等. 食品中类固醇激素基体标准物质研究进展[J]. 食品与机械, 2023, 39(1): 215-220. [13] 张苏敏, 邓文清, 徐雷, 等. 环境检测用六价铬溶液标准物质的研制及不确定度评定[J]. 计量与测试技术, 2023, 50(8): 106-109. [14] 施力予, 王晓文, 杨扬仲夫, 等. 环境监测用6种金属离子混合溶液标准物质的研制[J]. 中国测试, 2022, 48(8): 73-79. [15] 王振华. 环境监测分析中标准物质的选择及应用[J]. 化学分析计量, 2022, 31(4): 93-97. doi: 10.3969/j.issn.1008-6145.2022.04.019 [16] Zhou J, Yang M, Li F, et al. Development of matrix certified reference material for accurate determination of docosahexaenoic acid in milk powder[J]. Food Chem, 2023, 406: 135012. doi: 10.1016/j.foodchem.2022.135012 [17] Zhou J, Yan J, Qi X, et al. Development of a new matrix-certified reference material for accurate measurement of PFOA and PFOS in oyster meat powder[J]. Microchemical Journal, 2023, 190: 108673. doi: 10.1016/j.microc.2023.108673 [18] Zhou J, Wang M, Zhang L, et al. Development of a mutton powder certified reference material for the analysis of ractopamine[J]. Journal of Food Composition and Analysis, 2023, 115: 104935. doi: 10.1016/j.jfca.2022.104935 [19] Yang M, Li S, Wang M, et al. Study of a new matrix certified reference material for accurate measurement of pefloxacin in fish meat powder[J]. Microchemical Journal, 2022, 182: 107861. doi: 10.1016/j.microc.2022.107861 [20] Guo W, Meng J, Wang X, et al. Preparation and characterization of the aflatoxin B1 purity certified reference material (GBW (E) 100599)[J]. Microchemical Journal, 2024, 199: 109919. doi: 10.1016/j.microc.2024.109919 [21] 吴利君. 乳粉中地塞米松基体标准物质的研制[D]. 天津: 天津农学院, 2023. [22] 吴迪, 王继双, 张会亮, 等. 3-亚苄基樟脑国家化妆品标准物质的研制[J]. 日用化学品科学, 2022, 45(11): 28-31. [23] 刘彤彤, 金绍明, 曹进, 等. 乳液中氢醌的基体标准物质制备[J]. 化学分析计量, 2023, 32(9): 1-4. [24] Tahoun I, Gab-Allah M, Rend E. Preparation and value assignment of parabens and phenoxyethanol in cosmetic cream certified reference material[J]. J. Chem. Metrol, 2021, 15(1): 1-10. [25] Ng S Y, Dewi F, Wang J, et al. Development of a cosmetic cream certified reference material: Certification of lead, mercury and arsenic mass fractions in cosmetic cream[J]. International Journal of Mass Spectrometry, 2015, 389: 59-65. doi: 10.1016/j.ijms.2015.08.015 [26] 郭玲玲, 徐慧, 匡华. 食品安全检测基体标准物质研究进展[J]. 食品与生物技术学报, 2022, 41(7): 71-83. doi: 10.3969/j.issn.1673-1689.2022.07.007 [27] 周明慧, 伍燕湘, 李丽, 等. 粮油基体标准物质的研制、应用及展望[J]. 粮油食品科技, 2023, 31(5): 188-196. [28] 林若漫, 林振华. 生物毒素基体标准物质研究进展[J]. 食品安全导刊, 2022(35): 183-187. doi: 10.3969/j.issn.1674-0270.2022.35.spaqdk202235064 [29] 李硕, 李莉, 王海燕, 等. 我国化妆品标准及其效力研究[J]. 中国药事, 2021, 35(1): 29-36. [30] 中华人民共和国国务院. 化妆品监督管理条例(国令第727号)[EB/OL]. [2024-05-06]. https://www.gov.cn/zhengce/content/2020-06/29/content_5522593.htm. [31] 国家药品监督管理局. 国家药监局关于发布《化妆品分类规则和分类目录》的公告(2021年第49号)[EB/OL]. [2024-05-06]. https://www.nmpa.gov.cn/xxgk/ggtg/hzhpggtg/jmhzhptg/20210409160151122.html. [32] COMAR. COde d'Indexation des Matériaux de Référence [DB/OL]. [2024-05-27]. https://www.comar.bam.de. [33] NIST. National Institute of Standards and Technology of the United States. Standard reference materials [DB/OL]. [2024-05-27]. https://www.nist.gov/srm. [34] Joint Research Centre, Institute for Reference Materials and Measurements ( JRC-IRMM ). IRMM reference materials [DB/OL]. [2024-05-27]. https://crm.jrc.ec.europa.eu/. [35] LGC. Laboratory of the Government Chemist of the United Kingdom. Analytical reference materials, standards and high purity solvents [EB/OL]. [2024-05-27]. https://www.lgcstandards.com/CN/en/ [36] Bîrsan M, Stan C D, Mielcarek K, et al. Mercury exposure in cosmetics and human health risk[J]. Farmacia, 2023, 71(5): 930-937. doi: 10.31925/farmacia.2023.5.7 [37] Bamidele O D, Kayode B A, Eniayewu O I, et al. Quality assessment of hydroquinone, mercury, and arsenic in skin-lightening cosmetics marketed in Ilorin, Nigeria[J]. Scientific Reports, 2023, 13(1): 20992. doi: 10.1038/s41598-023-47160-2 [38] Saah S A, Boadi N O, Sakyi P O, et al. Risk of Exposure to Trace Elements through the Application of Facial Makeup Powders[J]. Journal of Chemistry, 2022, 2022: 1-6. [39] 中国食品药品检定研究院. 中检院关于公开征求《化妆品安全技术规范》修订意见的通知 附件1: 《化妆品安全技术规范(2022年版)》征求意见稿 [EB/OL]. [2024-05-06]. https://www.nifdc.org.cn/directory/web/nifdc/infoAttach/dcb0dc40-b6c9-4cad-87ed-be3db0c32ad7.pdf. [40] 国家药品监督管理局. 国家药监局关于将化妆品中激素类成分的检测方法和化妆品中抗感染类药物的检测方法纳入化妆品安全技术规范(2015年版)的通告(2019年第66号)[EB/OL]. [2024-05-06]. https://www.nmpa.gov.cn/hzhp/hzhpfgwj/hzhpgzwj/20190927152001264.html. [41] 国家药品监督管理局. 国家药监局关于将化妆品毒理学试验方法样品前处理通则等19项制修订项目纳入化妆品安全技术规范(2015年版)的通告(2024年第12号)[EB/OL]. [2024-05-06]. https://www.nmpa.gov.cn/xxgk/ggtg/hzhpggtg/jmhzhptg/20240321171624153.html. [42] 国家药品监督管理局. 国家药监局关于将化妆品中防腐剂检验方法等7项检验方法纳入化妆品安全技术规范(2015年版)的通告(2021年第17号)[EB/OL]. [2024-05-06]. https://www.nmpa.gov.cn/xxgk/ggtg/hzhpggtg/jmhzhptg/20210302174406138.html. [43] 杨扬仲夫. 2017~2021年我国国家标准物质获批情况剖析[J]. 计量与测试技术, 2023, 50(8): 58-61. -
下载:
点击查看大图
图(3)
计量
- 文章访问数: 100
- HTML全文浏览量: 37
- PDF下载量: 6
- 被引次数: 0
