Research Progress of Neonicotinoid Pesticides Certified Reference

TU Mengling; YANG Bingxin; ZHU Yunxiao; LI Xianjiang

doi:10.12338/j.issn.2096-9015.2023.0111

Volume 67 Issue 3

Mar. 2023

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TU Mengling, YANG Bingxin, ZHU Yunxiao, LI Xianjiang. Research Progress of Neonicotinoid Pesticides Certified Reference[J]. Metrology Science and Technology, 2023, 67(3): 65-71. doi: 10.12338/j.issn.2096-9015.2023.0111

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TU Mengling, YANG Bingxin, ZHU Yunxiao, LI Xianjiang. Research Progress of Neonicotinoid Pesticides Certified Reference[J]. Metrology Science and Technology, 2023, 67(3): 65-71. doi: 10.12338/j.issn.2096-9015.2023.0111

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Research Progress of Neonicotinoid Pesticides Certified Reference

doi: 10.12338/j.issn.2096-9015.2023.0111

TU Mengling^1
,,
YANG Bingxin^{1, 2},
ZHU Yunxiao^{1, 3},
LI Xianjiang^{1
,
,}

1.
National Institute of Metrology, Beijing 100029, China
2.
Beijing University of Chemical Technology, Beijing 100029, China
3.
China University of Petroleum, Beijing 102299, China

Received Date: 2023-04-18
Accepted Date: 2023-04-23
Rev Recd Date: 2023-04-24

Available Online: 2023-04-28

Publish Date: 2023-03-18

Abstract

Abstract

Neonicotinoid pesticides, characterized by high efficiency, broad-spectrum application, low toxicity, and remarkable selectivity, are now the most widely used insecticides worldwide. Nonetheless, these pesticides pose potential risks to the human nervous and reproductive systems through exposure via drinking water, food, and inhalation. This paper comprehensively summarizes the types, sample preparation techniques, and value assignment methodologies for certified reference materials (CRMs) of neonicotinoid pesticides, crucial for ensuring accurate, comparable, and traceable quantitative detection results. In China, CRMs primarily consist of purity and solution reference materials, chiefly incorporating acetamiprid and imidacloprid. However, there is a significant shortage of matrix reference materials. Purity CRMs are typically prepared by purifying commercially available materials, and their values are primarily assigned using mass balance methods and differential scanning calorimetry. Conversely, international institutes have developed a plethora of matrix CRMs for neonicotinoid pesticides, containing various analytes. These matrix samples are prepared by spiking blank or positive samples with the expected concentration of analytes and are subsequently quantified using liquid chromatography isotope dilution mass spectrometry (LC-ID-MS). The development of neonicotinoid pesticide CRMs in China lacks balance both in type and structure. Hence, the development of multi-component and multi-level matrix CRMs for neonicotinoid pesticides needs to be accelerated to improve the quantitative traceability system and meet the growing demand for extensive testing.
- metrology,
- nicotinoids,
- pesticides,
- certified reference materials,
- value assignment,
- liquid chromatography

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References(35)

References

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