基于红外吸收光谱技术的CO2同位素测量研究进展

    Research Progress on CO2 Isotope Measurement Based on Infrared Absorption Spectroscopy

    • 摘要: 全球气候变暖形势加剧,温室气体排放是关键因素之一。二氧化碳作为主要温室气体,对其高精度监测技术是实现温室气体追踪的基础。在此基础上监测二氧化碳同位素组份,不仅可以实现高精度浓度监测,还能够区分不同排放源的碳循环过程贡献,实现人为排放和自然排放的追踪和溯源。发展高精度二氧化碳同位素监测技术对提升碳排放清单准确性,优化碳减排措施等具有重要意义。在自然界中,碳同位素气体浓度通常为大气浓度的10−6倍,并受测量条件的影响,这导致了碳同位素测量难度加大。综述了红外吸收光谱技术测量二氧化碳稳定同位素浓度的研究进展,分析了高灵敏度稳频光腔衰荡光谱技术的原理及研究进展,并展望了稳定同位素光谱研究的未来方向。光腔衰荡光谱技术作为新兴光学检测技术,克服了传统方法测量精度不足、灵敏度低等缺陷,或成为新一代温室气体及同位素丰度测量标准方法。

       

      Abstract: The global warming situation has intensified, and greenhouse gas emissions are one of the key factors. Carbon dioxide, as the main greenhouse gas (GHG), requires high-precision monitoring technology as the basis for GHG tracking. On this basis, monitoring the carbon dioxide isotope composition not only enables high-precision concentration monitoring but also allows for distinguishing the contributions of different emission sources to the carbon cycle process, achieving the tracking and traceability of anthropogenic and natural emissions. Developing high-precision carbon dioxide isotope monitoring technology is of great significance for improving the accuracy of carbon emission inventories and optimizing carbon emission reduction measures. In nature, carbon isotope gas concentrations are usually on the order of 10−6 of atmospheric concentrations and are affected by measurement conditions, which leads to increased difficulty in carbon isotope measurements. This paper reviews the research progress of infrared absorption spectroscopy techniques for measuring carbon dioxide stable isotope concentrations, analyzes the principles and research progress of high-sensitivity frequency-stabilized cavity ring-down spectroscopy (FS-CRDS), and provides an outlook on the future direction of stable isotope spectroscopy research. As an emerging optical detection technology, FS-CRDS overcomes the shortcomings of traditional methods, such as insufficient measurement accuracy and low sensitivity, and may become a new generation of standard methods for measuring GHGs and isotope abundance.

       

    /

    返回文章
    返回