基于傅里叶红外光谱分析技术的便携式红外气体分析仪性能评价研究

    Performance Evaluation of a Portable Infrared Gas Analyser Based on Fourier Infrared Spectral Analysis Technique

    • 摘要: 评估了基于傅里叶红外光谱技术的便携式红外气体分析仪在环境和气体排放检测中的性能。该仪器由固态激光器、SiC红外光源、迈克尔逊干涉仪等组成,软件系统涵盖仪器管理、测量管理和数据管理模块,为高精度测量提供技术支持。通过溯源校准和不同浓度气体的测试对仪器性能进行了验证,测试气体包括C3H8、CO2、NO和NO2。实验设定测试气体浓度范围从20 μmol/mol降至1 μmol/mol,输出值与设定值接近,示值误差较小,其中C3H8的误差范围为−0.24 μmol/mol至0.02 μmol/mol,CO2的误差范围为−0.64 μmol/mol至0.12 μmol/mol,NO的误差范围为0.075 μmol/mol至0.12 μmol/mol,NO2 的误差范围为0.08 μmol/mol至0.15 μmol/mol。重复性测试显示,CO气体的10次测量标准偏差为0.04 μmol/mol。不确定度分析表明,C3H8、CO2、NO、NO2的相对扩展不确定度分别为1.43%(k=2)、1.45%(k=2)、1.53%(k=2)、1.43%(k=2),结果验证了仪器具有高准确性、良好的线性响应和测量可靠性,适用于环境监测和气体排放检测。尽管初步验证了仪器的应用潜力,但未能测试所有气体组分以及评估仪器长期稳定性,后续研究可扩展测试范围并进行长期评估。

       

      Abstract: The performance of a portable infrared gas analyzer based on Fourier transform infrared spectroscopy (FTIR) technology was evaluated for environmental monitoring and gas emission detection. The instrument comprises a solid-state laser, SiC infrared light source, Michelson interferometer, and software system incorporating instrument management, measurement management, and data management modules, providing technical support for high-precision measurements. Performance verification was conducted through traceability calibration and testing with various concentration gases including C3H8, CO2, NO, and NO2. Experimental tests spanned gas concentrations from 20 μmol/mol down to 1 μmol/mol, showing close agreement between measured values and setpoints with minor indication errors: C3H8 (−0.24 to 0.02) μmol/mol, CO2 (−0.64 to 0.12 )μmol/mol, NO (0.075 to 0.12 )μmol/mol, and NO2 (0.08 to 0.15) μmol/mol. Repeatability tests demonstrated a standard deviation of 0.04 μmol/mol for CO over 10 measurements. Uncertainty analysis revealed relative expanded uncertainties of 1.43% (k=2) for C3H8, 1.45% (k=2) for CO2, 1.53% (k=2) for NO, and 1.43% (k=2) for NO2. These results confirm the instrument's high accuracy, excellent linear response, and measurement reliability for environmental monitoring and emission detection applications. While preliminary validation demonstrates application potential, limitations include incomplete testing of all gas components and absence of long-term stability evaluation. Future research should expand test scope and conduct extended operational assessments.

       

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