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水环境中砷和锑检测方法的研究进展

于亚琴 周振 杜彪 卢小新 张正东

于亚琴,周振,杜彪,等. 水环境中砷和锑检测方法的研究进展[J]. 计量科学与技术,2022, 66(6): 19-25, 59 doi: 10.12338/j.issn.2096-9015.2021.0591
引用本文: 于亚琴,周振,杜彪,等. 水环境中砷和锑检测方法的研究进展[J]. 计量科学与技术,2022, 66(6): 19-25, 59 doi: 10.12338/j.issn.2096-9015.2021.0591
YU Yaqin, ZHOU Zhen, DU Biao, LU Xiaoxin, ZHANG Zhengdong. Research Progress of Arsenic and Antimony Detection Methods in Water Environment[J]. Metrology Science and Technology, 2022, 66(6): 19-25, 59. doi: 10.12338/j.issn.2096-9015.2021.0591
Citation: YU Yaqin, ZHOU Zhen, DU Biao, LU Xiaoxin, ZHANG Zhengdong. Research Progress of Arsenic and Antimony Detection Methods in Water Environment[J]. Metrology Science and Technology, 2022, 66(6): 19-25, 59. doi: 10.12338/j.issn.2096-9015.2021.0591

水环境中砷和锑检测方法的研究进展

doi: 10.12338/j.issn.2096-9015.2021.0591
基金项目: 国家市场监督管理总局科技计划项目(2021MK153);中国计量科学研究院博士后项目(BH2107);中国计量科学研究院基本科研业务费项目(AKYZZ2234)。
详细信息
    作者简介:

    于亚琴(1990-),中国计量科学研究院助理研究员,研究方向:环境分析化学,邮箱:yuyq@nim.ac.cn

    通讯作者:

    张正东(1976-),中国计量科学研究院副研究员,研究方向:分析化学,邮箱:zhangzhengdong@nim.ac.cn

Research Progress of Arsenic and Antimony Detection Methods in Water Environment

  • 摘要: 砷和锑是典型阴离子型污染物,随着砷锑矿产资源开发,以及含砷锑农药和添加剂的滥用,环境中砷和锑污染事件时有发生。环境介质中砷和锑形态分析技术的发展,对砷和锑污染环境监管和污染防治具有重要意义。对现有砷和锑的形态分析技术进行了综述,特别关注目前现场形态分析技术的发展,并指出环境样品中砷和锑赋存形态分析、在线监测开发的重要发展方向。
  • 图  1  含氧阴离子砷和锑(三价和五价)的分子结构示意图

    Figure  1.  Schematic diagram of molecular structures of the oxygen-containing anions arsenic and antimony (trivalent and pentavalent)

    图  2  Visual MINTEQ 3.1模拟不同pH下砷和锑赋存形态的理论分布图[12]

    Figure  2.  Visual MINTEQ 3.1 simulated theoretical distribution of arsenic and antimony species at different pH

    图  3  高砷地区在世界范围的分布[14]

    Figure  3.  Location of high arsenic areas in the world[14]

    图  4  二氧化硅纳米颗粒[24]和基于量子点[25]的荧光传感器分析三价砷

    Figure  4.  Silicon dioxide nanoparticles [24]and quantum dot-based[25] fluorescent sensors for the analysis of trivalent arsenic

    图  5  基于阳离子盐诱导AuNPs聚集的传感器检测水溶液中As(III)[28]

    Figure  5.  Sensor based on cationic salt-induced aggregation of AuNPs for detection of As(III) in aqueous solution[28]

    图  6  Au@Ag[31]、Fe3O4@Ag[32]核壳结构纳米颗粒对As(III)的SERS检测以及 I3-Ag-VBB对Sb(III)的SERS检测[36]

    Figure  6.  SERS detection of As(III) based on Au@Ag[31] and Fe3O4@Ag[32] core–shell nanoparticles, and SERS detection of Sb(III) based on I3-Ag-VBB[36]

    图  7  3D还原氧化石墨烯修饰AuNPs传感器[37]、双金属电极[38], 钌修饰玻碳电极[39]用于检测As(III)以及核壳结构AuFe@FeOx-CFC柔性电极材料[22]测定Sb(III)

    Figure  7.  Sensors based on 3D-reduced graphene oxide modified AuNPs[37], bimetallic electrode[38], ruthenium modified glass carbon electrode for As(III) determination[39], and core-shell AuFe@FeOx-CFC flexible electrode for Sb(III) determination[22]

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  • 录用日期:  2022-03-22
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