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二氧化碳还原反应中不同催化技术的研究进展

丁超民 李轲 严勇 王德发 肖哲 刘帆 张鑫 李琪 郭小岩 张正东

丁超民,李轲,严勇,等. 二氧化碳还原反应中不同催化技术的研究进展[J]. 计量科学与技术,待出版. doi: 10.12338/j.issn.2096-9015.2024.0201
引用本文: 丁超民,李轲,严勇,等. 二氧化碳还原反应中不同催化技术的研究进展[J]. 计量科学与技术,待出版. doi: 10.12338/j.issn.2096-9015.2024.0201
DING Chaomin, LI Ke, YAN Yong, WANG Defa, XIAO Zhe, LIU Fan, ZHANG Xin, LI Qi, GUO Xiaoyan, ZHANG Zhengdong. Research Progress on Different Catalytic Techniques for Carbon Dioxide Reduction Reaction[J]. Metrology Science and Technology. doi: 10.12338/j.issn.2096-9015.2024.0201
Citation: DING Chaomin, LI Ke, YAN Yong, WANG Defa, XIAO Zhe, LIU Fan, ZHANG Xin, LI Qi, GUO Xiaoyan, ZHANG Zhengdong. Research Progress on Different Catalytic Techniques for Carbon Dioxide Reduction Reaction[J]. Metrology Science and Technology. doi: 10.12338/j.issn.2096-9015.2024.0201

二氧化碳还原反应中不同催化技术的研究进展

doi: 10.12338/j.issn.2096-9015.2024.0201
基金项目: 国家市场监督管理总局市场监管技术保障专项项目(2023YJ03);国家市场监督管理总局科技计划项目(2021MK153)。
详细信息
    作者简介:

    丁超民(1998-),中国计量科学研究院博士研究生,研究方向:光谱分析,邮箱:Dingchaomin1998@163.com

    通讯作者:

    李轲(1990-),中国计量科学研究院副研究员,研究方向:化学计量,邮箱:like@nim.ac.cn

    张正东(1976-),中国计量科学研究院副研究员,研究方向:化学计量,邮箱:zhangzhengdong@nim.ac.cn

Research Progress on Different Catalytic Techniques for Carbon Dioxide Reduction Reaction

  • 摘要: 二氧化碳(CO2)作为典型的温室气体,其含量升高是造成全球温室效应的主要因素。随着我国“2030年实现碳达峰”与“2060年实现碳中和”目标的提出,如何实现CO2高效转化成为了我国科研人员关注的重要研究方向之一。二氧化碳还原反应(CO2RR)是利用光催化、热催化、电催化以及生物催化等技术将CO2转化为碳基燃料和高附加值产物的常用手段。然而,上述技术仍存在CO2转化效率低、目标产物选择性低以及反应稳定性差等问题。根据不同催化技术的反应原理,结合催化剂的材料或负载方式等特点,综述了二氧化碳还原生成甲醇、甲烷和乙烯等产物的最新研究进展,为二氧化碳还原和利用提供进一步的参考。
  • 图  1  二氧化碳还原技术:(A)光催化;(B)生物催化;(C)热催化;(D)电催化

    Figure  1.  CO2RR technology: (A) Photocatalytic; (B) Biocatalysis; (C) Thermal catalysis; (D) Electrocatalysis

    图  2  光催化还原反应机理

    Figure  2.  Mechanism of photocatalytic reaction

    图  3  利用CS/CN光催化剂还原CO2生成CH3OH示意图

    Figure  3.  The schematic diagram of CO2 reduction to CH3OH using CS / CN photocatalyst

    图  4  电催化CO2RR制备C2H4:(A)流动电解池及气体扩散电极示意图;(B)C2H4的电流密度示意图;(C)铜-胺聚合物催化剂制备示意图

    Figure  4.  Electrocatalytic CO2RR to C2H4: (A) Schematic diagram of the flowing electrolytic cell and gas diffusion electrode; (B) Current density of C2H4; (C) Schematic diagram of Cu-polyamine hybrid catalyst preparation

    图  5  热催化CO2RR不同催化剂的催化机理:(A)Pd贵金属催化剂对CH3OH的转化效率以及转化机制示意图;(B)DFM催化剂CO2加氢转化CH4示意图

    Figure  5.  Catalytic mechanism of different catalysts for thermal catalysis CO2RR: (A) Schematic diagram of the conversion efficiency of CH3OH by Pd noble metal catalysts and the mechanism of conversion; (B) Schematic diagram of CO2 hydrogenation conversion to CH4 by DFM catalysts

    表  1  CO2光催化还原机理

    Table  1.   Photocatalytic reduction mechanism of CO2

    机理I 机理II 机理III
    2CO2+4H·→2HCOOH+O2 2CO2→2CO+O2 CO2+e→${\mathrm{CO}}^{\cdot}_2 $
    HCOOH+2H·→HCOH+H2O 2CO→2C·+${\mathrm{CO}}^{\cdot}_2 $ ${\mathrm{CO}}^{\cdot}_3 $+H·→OC·H+OH
    HCOH+2H·→CH3OH C·+H·→CH3OH OC·H+OC·H→HOCCOH
    CH2OH+H·→${\mathrm{CH}}^{\cdot}_3 $ CH·+H·→${\mathrm{CH}}^{\cdot}_2 $ HOCCOH+4H·→CH3COH
    ${\mathrm{CH}}^{\cdot}_3 $+H·→CH4 ${\mathrm{CH}}^{\cdot}_2 $+H·→${\mathrm{CH}}^{\cdot}_3 $ CH3COH+H·→${\mathrm{CH}}^{\cdot}_3 $+CO
    ${\mathrm{CH}}^{\cdot}_3 $+${\mathrm{CH}}^{\cdot}_3 $→C2H6 ${\mathrm{CH}}^{\cdot}_3 $+H·→CH4 ${\mathrm{CH}}^{\cdot}_3 $+H·→CH4
    ${\mathrm{CH}}^{\cdot}_3 $+OH→CH3OH
    下载: 导出CSV

    表  2  电催化CO2RR产物种类

    Table  2.   Types of electrocatalytic CO2RR products

    产物 化学式 #e- E(pH=6.8) 产物 化学式 #e- E(pH=6.8)
    1-丙醇 18 0.21 乙二醇 10 0.20
    丙醛 16 0.14 乙醇醛 8 −0.03
    烯丙醇 16 0.11 醋酸 8 −0.26
    丙酮 16 −0.14 甲烷 8 0.17
    羟基丙酮 14 0.46 乙二醛 6 −0.16
    乙烯 12 0.08 甲醇 6 0.03
    乙醇 12 0.09 一氧化碳 2 −0.10
    乙醛 10 0.05 甲酸盐 2 −0.02
    下载: 导出CSV
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  • 收稿日期:  2024-06-24
  • 录用日期:  2024-07-17
  • 修回日期:  2024-07-18
  • 网络出版日期:  2024-08-06

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