Research Progress of Graphene Quantum Dots and Graphene Quantum Dots Reference Materials
-
摘要: 石墨烯量子点是指横向尺寸小于30 nm,片层层数在10层以下的一种新型的荧光碳材料,由于其独特的特性和广阔的应用前景,受到了广泛的关注。主要介绍了石墨烯量子点的结构、电学和光学特性,总结了目前石墨烯量子点的主要制备方法,对其在新能源、催化、传感、生物医药、环境修复等方面的应用进行了详细的介绍,最后对石墨烯量子点标准物质的研究进展进行了简单的介绍。未来对石墨烯量子点的研究主要集中在提高光致发光量子产率和生产量,以及拓展其应用范围和制备石墨烯量子点标准物质上,随着新材料设计理念的进步和量子技术的不断发展,石墨烯量子点及其标准物质有望在更多领域展现出其独特的优势和应用价值。Abstract: Graphene quantum dots refer to a new type of fluorescent carbon material with a transverse size of less than 30 nm and a layer number of less than 10 layers. Due to their unique characteristics and broad application prospects, graphene quantum dots have received extensive attention. In this paper, the unique structure, electrical and optical properties of graphene quantum dots are introduced, the main preparation methods of graphene quantum dots are summarized, and their applications in new energy, catalysis, sensing, biomedicine and environmental remediation are introduced in detail. Finally, the research progress of graphene quantum dots standard materials is briefly introduced. Future research on graphene quantum dots is mainly focused on improving the photoluminescent quantum yield and manufacturing output, as well as expanding the application range and preparing graphene quantum dot standard materials. With the progress of new material design concepts and the continuous development of quantum technology, graphene quantum dots and their standard materials are expected to show their unique advantages and application value in more fields.
-
[1] Sheikh Mohd Ghazali SAI, Fatimah I, Zamil ZN, et al. Graphene quantum dots: A comprehensive overview[J]. Open Chemistry, 2023, 21(1). [2] Nxele SR, Nyokong T. Time-dependent characterization of graphene quantum dots and graphitic carbon nitride quantum dots synthesized by hydrothermal methods[J]. Diamond and Related Materials, 2022, 121. [3] Rabeya R, Mahalingam S, Manap A, et al. Structural defects in graphene quantum dots: A review[J]. International Journal of Quantum Chemistry, 2022, 122(12). [4] Raghavan A, Radhakrishnan M, Soren K, et al. Biological Evaluation of Graphene Quantum Dots and Nitrogen-Doped Graphene Quantum Dots as Neurotrophic Agents[J]. ACS Applied Bio Materials, 2023, 6(6): 2237-2247. doi: 10.1021/acsabm.3c00099 [5] Rani P, Dalal R, Srivastava S, et al. Tuning the properties of graphene quantum dots by passivation[J]. Physical Chemistry Chemical Physics, 2022, 24(42): 26232-26240. doi: 10.1039/D2CP03990G [6] Tan X, Zhou F, Li W, et al. Research Progress on the Application of Graphene Quantum Dots[J]. Coatings, 2023, 13(11). [7] Chen W, Lv G, Hu W, et al. Synthesis and applications of graphene quantum dots: a review[J]. Nanotechnology Reviews, 2018, 7(2): 157-185. doi: 10.1515/ntrev-2017-0199 [8] Ansari SA. Graphene Quantum Dots: Novel Properties and Their Applications for Energy Storage Devices[J]. Nanomaterials, 2022, 12(21). [9] Thai V-P, Tran DN, Kosugi K, et al. One-Step Synthesis of N-Doped Graphene Quantum Dots via Plasma Contacting Liquid for Multiple Heavy Metal Ion Detection[J]. ACS Applied Nano Materials, 2024, 7(11): 12664-12672. doi: 10.1021/acsanm.4c01134 [10] Ponomarenko LA, Schedin F, Katsnelson MI, et al. Chaotic Dirac Billiard in Graphene Quantum Dots[J]. Science, 2008, 320(5874): 356-358. doi: 10.1126/science.1154663 [11] Ji Z, Dervishi E, Doorn SK, et al. Size-Dependent Electronic Properties of Uniform Ensembles of Strongly Confined Graphene Quantum Dots[J]. The Journal of Physical Chemistry Letters, 2019, 10(5): 953-959. doi: 10.1021/acs.jpclett.9b00119 [12] Zhu S, Wang L, Li B, et al. Investigation of photoluminescence mechanism of graphene quantum dots and evaluation of their assembly into polymer dots[J]. Carbon, 2014, 77: 462-472. doi: 10.1016/j.carbon.2014.05.051 [13] Qian J, Shen C, Yan J, et al. Tailoring the Electronic Properties of Graphene Quantum Dots by P Doping and Their Enhanced Performance in Metal-Free Composite Photocatalyst[J]. The Journal of Physical Chemistry C, 2017, 122(1): 349-358. [14] Deng J, Lu Q, Li H, et al. Large scale preparation of graphene quantum dots from graphite oxide in pure water via one-step electrochemical tailoring[J]. RSC Advances, 2015, 5(38): 29704-29707. doi: 10.1039/C4RA16805D [15] Liang L, Kong Z, Kang Z, et al. Theoretical Evaluation on Potential Cytotoxicity of Graphene Quantum Dots[J]. ACS Biomaterials Science & Engineering, 2016, 2(11): 1983-1991. [16] Chong Y, Ma Y, Shen H, et al. The in vitro and in vivo toxicity of graphene quantum dots[J]. Biomaterials, 2014, 35(19): 5041-5048. doi: 10.1016/j.biomaterials.2014.03.021 [17] Xie Y, Wan B, Yang Y, et al. Cytotoxicity and autophagy induction by graphene quantum dots with different functional groups[J]. Journal of Environmental Sciences, 2019, 77: 198-209. doi: 10.1016/j.jes.2018.07.014 [18] Dong Y, Shao J, Chen C, et al. Blue luminescent graphene quantum dots and graphene oxide prepared by tuning the carbonization degree of citric acid[J]. Carbon, 2012, 50(12): 4738-4743. doi: 10.1016/j.carbon.2012.06.002 [19] Qu D, Zheng M, Du P, et al. Highly luminescent S, N co-doped graphene quantum dots with broad visible absorption bands for visible light photocatalysts[J]. Nanoscale, 2013, 5(24). [20] Zhang C, Cui Y, Song L, et al. Microwave assisted one-pot synthesis of graphene quantum dots as highly sensitive fluorescent probes for detection of iron ions and pH value[J]. Talanta, 2016, 150: 54-60. doi: 10.1016/j.talanta.2015.12.015 [21] Vu Tuyet Nhung T, Van Tuyen H, Tran N, et al. S, N co-doped graphene quantum dots fabricated by rapid microwave-assisted pyrolysis and their optical properties[J]. Materials Today Communications, 2023, 37. [22] Budak E, Aykut S, Paşaoğlu ME, et al. Microwave assisted synthesis of boron and nitrogen rich graphitic quantum dots to enhance fluorescence of photosynthetic pigments[J]. Materials Today Communications, 2020, 24. [23] Tang L, Ji R, Li X, et al. Size‐Dependent Structural and Optical Characteristics of Glucose‐Derived Graphene Quantum Dots[J]. Particle & Particle Systems Characterization, 2013, 30(6): 523-531. [24] Wen J, Li M, Xiao J, et al. Novel oxidative cutting graphene oxide to graphene quantum dots for electrochemical sensing application[J]. Materials Today Communications, 2016, 8: 127-133. doi: 10.1016/j.mtcomm.2016.07.006 [25] Huang H, Yang S, Li Q, et al. Electrochemical Cutting in Weak Aqueous Electrolytes: The Strategy for Efficient and Controllable Preparation of Graphene Quantum Dots[J]. Langmuir, 2017, 34(1): 250-258. [26] Ganganboina AB, Doong R-A. Nitrogen doped graphene quantum dot-decorated earth-abundant nanotubes for enhanced capacitive deionization[J]. Environmental Science: Nano, 2020, 7(1): 228-237. doi: 10.1039/C9EN00852G [27] Gebreegziabher GG, Asemahegne AS, Ayele DW, et al. Polyaniline–graphene quantum dots (PANI–GQDs) hybrid for plastic solar cell[J]. Carbon Letters, 2019, 30(1): 1-11. [28] AlSalem HS, Katubi KMS, Binkadem MS, et al. Fabrication of Asymmetric Supercapacitors (AC@GQDs//AC) with High Electrochemical Performance Utilizing Activated Carbon and Graphene Quantum Dots[J]. ACS Omega, 2023, 8(43): 40808-40816. doi: 10.1021/acsomega.3c05882 [29] Gong L, Yang R, Liu R, et al. Chemical synthesis of dendritic interlaced network graphene quantum dots/sulfur composite for lithium-sulfur batteries[J]. Journal of Alloys and Compounds, 2021, 855. [30] Shan C, Liu Z, Li F, et al. Ternary TiO2/P-GQDs/AgI nanocomposites with n-p-n heterojunctions for enhanced visible photocatalysis[J]. Journal of Nanoparticle Research, 2023, 25(7). [31] Guo Q, Feng J, Liu H, et al. Effects of hydronium and hydroxide ion/group on oxygen reduction reaction electrocatalytic activities of N-doped graphene quantum dots[J]. Molecular Catalysis, 2022, 517. [32] Liu Z, Cai X, Lin X, et al. Signal-on fluorescent sensor based on GQDs–MnO2 composite for glutathione[J]. Analytical Methods, 2016, 8(11): 2366-2374. doi: 10.1039/C5AY03108G [33] Kulandaiswamy AJ, Sharma N, Nesakumar N, et al. S, N‐GQDs Enzyme Mimicked Electrochemical Sensor to Detect the Hazardous Level of Monocrotophos in Water[J]. Electroanalysis, 2019, 32(5): 971-977. [34] Li Z, Cheng Z, Wang Y, et al. Single-layer graphene based resistive humidity sensor enhanced by graphene quantum dots[J]. Nanotechnology, 2024, 35(18). [35] Li B, Xiao X, Hu M, et al. Mn, B, N co-doped graphene quantum dots for fluorescence sensing and biological imaging[J]. Arabian Journal of Chemistry, 2022, 15(7). [36] Shi S-C, Liu H-H, Chen T-H, et al. Preparation of aldehyde-graphene quantum dots from glucose for controlled release of anticancer drug[J]. Frontiers in Materials, 2023, 10. [37] Raj SK, Yadav V, Bhadu GR, et al. Synthesis of highly fluorescent and water soluble graphene quantum dots for detection of heavy metal ions in aqueous media[J]. Environmental Science and Pollution Research, 2020, 28(34): 46336-46342. [38] Anusuya T, Kumar V, Kumar V. Hydrophilic graphene quantum dots as turn-off fluorescent nanoprobes for toxic heavy metal ions detection in aqueous media[J]. Chemosphere, 2021, 282.
点击查看大图
计量
- 文章访问数: 126
- HTML全文浏览量: 29
- PDF下载量: 11
- 被引次数: 0