Volume 65 Issue 6
Jul.  2021
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PENG Zijuan, SONG Shanjun, SHAO Mingwu. Study on Determination of Decabromodiphenyl Ether in a Matrix of Plastic Certified Reference Material[J]. Metrology Science and Technology, 2021, 65(6): 45-48. doi: 10.12338/j.issn.2096-9015.2020.9040
Citation: PENG Zijuan, SONG Shanjun, SHAO Mingwu. Study on Determination of Decabromodiphenyl Ether in a Matrix of Plastic Certified Reference Material[J]. Metrology Science and Technology, 2021, 65(6): 45-48. doi: 10.12338/j.issn.2096-9015.2020.9040

Study on Determination of Decabromodiphenyl Ether in a Matrix of Plastic Certified Reference Material

doi: 10.12338/j.issn.2096-9015.2020.9040
  • Available Online: 2021-05-08
  • Publish Date: 2021-07-08
  • Plastic has become a common material in our daily life. The influence of a plastic additive, decabromodiphenyl ether (BDE-209), on the environment and human health has gradually attracted worldwide attention. The pretreatment of complex matrix such as plastic is very important for accurate qualitative and quantitative analyses of target compounds. In this study, the extraction and analysis of the target BDE-209 in a matrix of polyethylene (PE) plastic Certified Reference Material (CRM) by using Agilent 1290 HPLC-DAD were carried out. By optimizing the pretreatments process, the problem of plastic dissolution and precipitation was solved, and the final sample solution could be detected and analyzed by using Agilent 1290 HPLC-DAD. Good accuracy and stability of the detection results were obtained. RSD was less than 3.9%. The LOD (S/N=3) and LOQ (S/N=10) of decabromodiphenyl ether were 0.017 μg·mL−1 and 0.05 μg·mL−1, respectively. The linear range of BDE-209 was 0.5 μg·mL−1~50.0 μg·mL−1 with R2=0.999. The method can be applied to quantitative analysis of CRM candidates such as polypropylene (PP) and acrylonitrile-butadiene-styrene (ABS).
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  • [1]
    P. Hennebert, M. Filella. WEEE plastic sorting for bromine essential to enforce EU regulation[J]. Waste Management, 2018, 71(GC-MS): 390-399.
    [2]
    Bingbing Sun, Yuanan Hu, Hefa Cheng, et al. Kinetics of Brominated Flame Retardant (BFR) Releases from Granules of Waste Plastics[J]. Environmental Science & Technology, 2016, 50(24): 13419-13427.
    [3]
    郑明辉, 谭丽, 高丽荣, 等. 履行《关于持久性有机污染物的斯德哥尔摩公约》成效评估监测进展[J]. 中国环境监测, 2019, 35(1): 1-7.
    [4]
    Stubbings W. A., S. Harrad. Factors influencing leaching of PBDEs from waste cathode ray tube plastic housings[J]. Science of The Total Environment, 2016, 569: 1004-1012.
    [5]
    Honggang Ni, Shaoyou Lu, Ting Mo, et al. Brominated flame retardant emissions from the open burning of five plastic wastes and implications for environmental exposure in China[J]. Environmental pollution, 2016, 214: 70-76. doi: 10.1016/j.envpol.2016.03.049
    [6]
    Hoang Quoc Anh, Vu Duc Nam, Tran Manh Tri, et al. Polybrominated diphenyl ethers in plastic products, indoor dust, sediment and fish from informal e-waste recycling sites in Vietnam: a comprehensive assessment of contamination, accumulation pattern, emissions, and human exposure[J]. Environmental geochemistry and health, 2017, 39(4): 935-954. doi: 10.1007/s10653-016-9865-6
    [7]
    Kate Hoffman, Thomas F Webster, Andreas Sjödin, et al. Toddler’s behavior and its impacts on exposure to polybrominated diphenyl ethers[J]. Journal of Exposure Science and Environmental Epidemiology, 2017, 27(2): 193. doi: 10.1038/jes.2016.11
    [8]
    Yuwei Wang, Yanmin Sun, Tian Chen, et al. Determination of polybrominated diphenyl ethers and novel brominated flame retardants in human serum by gas chromatography-atmospheric pressure chemical ionization-tandem mass spectrometry[J]. Journal of Chromatography B-Analytical Technologies in the Biomedical and Life Sciences, 2018, 1099: 64-72. doi: 10.1016/j.jchromb.2018.09.015
    [9]
    Qiqing Chen, Julia Reisser, Serena Cunsolo, et al. Pollutants in Plastics within the North Pacific Subtropical Gyre[J]. Environmental Science & Technology, 2018, 52(2): 446-456.
    [10]
    Jingjing Zhang, Yu Chen, Wenying Wu, et al. Hollow porous dummy molecularly imprinted polymer as a sorbent of solid-phase extraction combined with accelerated solvent extraction for determination of eight bisphenols in plastic products[J]. Microchemical Journal, 2019, 145: 1176-1184. doi: 10.1016/j.microc.2018.12.031
    [11]
    Yuan Chen, Jinhui Li, Lieqiang Chen, et al. Brominated flame retardants (BFRs) in waste electrical and electronic equipment (WEEE) plastics and printed circuit boards (PCBs)[J]. Procedia environmental sciences, 2012, 16: 552-559. doi: 10.1016/j.proenv.2012.10.076
    [12]
    Shao Mingwu, Wei Chao, Jia Yongjuan, et al. Determination of selected polybrominated diphenylethers and polybrominated biphenyl in polymers by ultrasonic-assisted extraction and high-performance liquid chromatography-inductively coupled plasma mass spectrometry[J]. Anal Chem, 2010, 82(12): 5154-5159. doi: 10.1021/ac1003618
    [13]
    Chuanyang Cai, ShuangyuYu Yu, Liu Yu, et al. PBDE emission from E-wastes during the pyrolytic process: Emission factor, compositional profile, size distribution, and gas-particle partitioning[J]. Environ Pollut, 2018, 235: 419-428. doi: 10.1016/j.envpol.2017.12.068
    [14]
    James H. Bridson, Evamaria C. Gaugler, Dawn A. Smith, et al. Leaching and extraction of additives from plastic pollution to inform environmental risk: A multidisciplinary review of analytical approaches[J]. Journal of Hazardous Materials, 2021, 414: 125571. doi: 10.1016/j.jhazmat.2021.125571
    [15]
    宋学君. 聚苯乙烯泡沫塑料回收与改性利用的研究[D]. 沈阳: 东北大学, 2006.
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